Chiride ya Zirconium, bizwi kandi nkazirconium (IV) chloride or ZrCl4, ni uruvange rusanzwe rukoreshwa mu nganda zitandukanye nubushakashatsi bwa siyansi.Nibintu byera bya kristaline ikomeye hamwe na molekuline yaZrCl4n'uburemere bwa molekile ya 233.09 g / mol.Chiride ya Zirconiumni reaction cyane kandi ifite uburyo bwinshi bwo gukoresha, uhereye kuri catalizator hamwe na synthesis ya chimique kugeza kubyara ceramika nikirahure.Muri iyi ngingo, tuzareba uburyozirconium chlorideni.
Synthesis yazirconium chloridebirimo reaction hagatizirconiumcyangwa zirconium icyuma na hydrogen chloride.Zirconiya (ZrO2) isanzwe ikoreshwa nkibikoresho byo gutangira bitewe no kuboneka no gutuza.Igisubizo kirashobora gukorwa imbere yumukozi ugabanya nka karubone cyangwa hydrogène kugirango ateze imbere ihindukazirconium oxyde intozirconium.
Icya mbere,zirconiaivanze na agent igabanya igashyirwa mubikoresho bya reaction.Gazi ya hydrogène chloride noneho yinjizwa mubwato bwa reaction, bigatuma reaction iba.Imyitwarire irashobora kuba idasanzwe, bivuze ko irekura ubushyuhe, kandi igomba gukorwa mubihe byagenzuwe kugirango hirindwe ingaruka zose.Igisubizo hagatizirconiumna hydrogen chloride ni iyi ikurikira:
ZrO2 + 4HCl → ZrCl4 + 2H2O
Ubusanzwe reaction ikorwa mubushyuhe bwinshi, mubisanzwe hagati ya dogere selisiyusi 400 na 600, kugirango ihindure ryuzuyezirconiuminzirconium chloride.Igisubizo kirakomeza kugeza bosezirconiumni Byahinduwe Kurizirconium (IV) chloriden'amazi.
Iyo reaction irangiye, ibivanze bivanze birakonja kandizirconium chlorideni Byegeranijwe.Ariko,zirconium chloridemubisanzwe ibaho muburyo bwamazi, bivuze ko irimo molekile zamazi muburyo bwa kristu.Kubonaanhydrous zirconium chloride, hydratedzirconium chlorideubusanzwe ashyushye cyangwa vacuum yumye kugirango ikureho molekile zamazi.
Ubuziranenge bwazirconium chlorideni ngombwa kuri porogaramu zihariye.Kubwibyo, izindi ntambwe zo kwezwa zishobora gusabwa gukuraho umwanda cyangwa ubuhehere.Ubuhanga busanzwe bwo kweza burimo sublimation, uduce duto duto, hamwe na distillation.Ubu buryo burashobora gukuramozirconium chloride, ni ingenzi ku nganda zinyuranye zirimo ibikoresho bya elegitoroniki no gukoresha ingufu za kirimbuzi.
Guteranya,zirconium chlorideni Byahinduwe na reaction yazirconiumhydrogène chloride.Iyi reaction isaba ibintu byagenzuwe kandi mubisanzwe bikorwa mubushyuhe bwinshi.Ibisubizozirconium chlorideisanzwe iboneka muburyo bwamazi, hamwe nintambwe zinyongera zisabwa kugirango ubone chloride ya anhydrous zirconium.Uburyo bwo kweza bushobora gukoreshwa kugirango ubone ibyerazirconium chlorideKuri Porogaramu.Umusaruro wazirconium chlorideni inzira y'ingenzi, kuyikoresha cyane mu nganda zitandukanye n'ubushakashatsi bwa siyansi.
Igihe cyo kohereza: Ugushyingo-10-2023