Zirconium (IV) chloride, bizwi kandi nkazirconium tetrachloride, ifite formulaire ya ZrCl4 nuburemere bwa 233.04.Ahanini ikoreshwa nka reagent isesengura, catalizike ya catalizike, ibikoresho bitarinda amazi, ibikoresho byo gutwika
Izina RY'IGICURUZWA:Chiride ya Zirconium; Zirconium tetrachloride;Zirconium (IV) chloride
Uburemere bwa molekuline: 233.04
EINECS: 233-058-2
Ingingo yo guteka: 331 (sublimation)
Ubucucike: 2.8
Imiti yimiti:ZrCl4
URUBANZA:10026-11-6
Ingingo yo gushonga: 437
Amazi meza: Kubora mumazi akonje
1.Umutungo
Imiterere yumubiri nubumara
1. Imiterere: Ikirahuri cyera kirabagirana cyangwa ifu, byoroshye gutanga.
2. Ingingo yo gushonga (℃): 437 (2533.3kPa)
3. Guteka (℃): 331 (sublimation)
4. Ubucucike bugereranijwe (amazi = 1): 2.80
5. Umuvuduko wumwuka wumuyaga (kPa): 0.13 (190 ℃)
6. Umuvuduko ukomeye (MPa): 5.77
7. Gukemura: Gushonga mumazi akonje, Ethanol, na ether, kudashonga muri benzene, tetrachloride ya karubone, na disulfide ya karubone.
Biroroshye kwinjiza ubuhehere nubushuhe, hydrolyz muri hydrogène chloride na zirconium oxychloride mumuyaga mwinshi cyangwa igisubizo cyamazi, ikigereranyo niki gikurikira:
Igihagararo
1. Igihagararo: gihamye
2. Ibintu bibujijwe: amazi, amine, alcool, acide, esters, ketone
3. Ibisabwa kugirango wirinde guhura: umwuka wuzuye
4. Impanuka ya polymerisation: non polymerisation
5. Ibicuruzwa byangirika: chloride
Gusaba
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3.Uburyo bwa sintetike
Gupima zirconi no kubara karubone yumukara ukurikije igipimo cya molarike yo gupima, vanga neza hanyuma ubishyire mubwato bwa farashi.Shira ubwato bwa farufari mu muyoboro wa farashi hanyuma ubishyuhe kugeza kuri 500 ℃ mumigezi ya chlorine kugirango ubare.Kusanya ibicuruzwa ukoresheje umutego mubushyuhe bwicyumba.Urebye sublimation ya zirconium tetrachloride kuri 331 ℃, umuyoboro muremure wa 600mm urashobora gukoreshwa kugirango wongere ugabanuke mumigezi ya hydrogène kuri 300-350 ℃ kugirango ukureho okiside na chloride ferric muri chloride ya zirconium.
4. Ingaruka ku bidukikije
Ibyangiza ubuzima
Inzira yo gutera: guhumeka, kuribwa, guhuza uruhu.
Ibyago byubuzima: Guhumeka birashobora gutera uburwayi bwubuhumekero, ntumire.Ifite uburakari bukomeye kandi irashobora gutera uruhu no kwangiza amaso.Ubuyobozi bwo mu kanwa bushobora gutera umunwa mu kanwa no mu muhogo, isesemi, kuruka, intebe y'amazi, intebe zamaraso, gusenyuka, no guhungabana.
Ingaruka zidakira: Zitera uruhu granuloma.Kurakara byoroheje inzira y'ubuhumekero.
Uburozi n'ibidukikije
Uburozi bukabije: LD501688mg / kg (ubuyobozi bwo mu kanwa ku mbeba);665mg / kg (imbeba yo mu kanwa)
Ibiranga akaga: Iyo bikorewe ubushyuhe cyangwa amazi, birabora kandi birekura ubushyuhe, birekura umwotsi wubumara kandi ubora.
Gutwika (decomposition) ibicuruzwa: hydrogen chloride.
Uburyo bwo gukurikirana laboratoire: Plasma spectroscopy (uburyo bwa NIOSH 7300)
Kwiyemeza mu kirere: gukusanya icyitegererezo ukoresheje akayunguruzo, kugishonga ukoresheje aside, hanyuma ukapima hamwe na atomic absorption spectroscopy.
Ibipimo by’ibidukikije: Ubuyobozi bushinzwe umutekano n’ubuzima (1974), Ikirere cyapimwe Ikigereranyo cya 5.
Ibisubizo byihutirwa
Tandukanya agace kanduye, ushireho ibimenyetso byo kuburira hirya no hino, kandi usabe abashinzwe ubuvuzi bwihutirwa kwambara mask ya gaze n imyenda ikingira imiti.Ntukajye uhura neza nibintu byasohotse, irinde umukungugu, ubisukure neza, utegure igisubizo cyamazi agera kuri 5% cyangwa acide, gahoro gahoro wongeremo amazi ya ammonia kugeza igihe imvura iguye, hanyuma ukayijugunya.Urashobora kandi kwoza n'amazi menshi, hanyuma ukayungurura amazi yo gukaraba muri sisitemu y'amazi.Niba hari umubare munini wo kumeneka, iyikureho uyobowe nabakozi ba tekinike.Uburyo bwo kujugunya imyanda: Vanga imyanda na sodium bicarbonate, utere amazi ya amoniya, hanyuma ushyiremo urubura rwajanjaguwe.Iyo reaction imaze guhagarara, kwoza amazi mumazi.
Ingamba zo gukingira
Kurinda ubuhumekero: Iyo hagaragaye umukungugu, mask ya gaze igomba kwambara.Wambare ibikoresho byo guhumeka byonyine mugihe bibaye ngombwa.
Kurinda amaso: Kwambara amadarubindi yumutekano.
Imyenda ikingira: Wambare imyenda y'akazi (ikozwe mubikoresho birwanya ruswa).
Kurinda intoki: Kwambara uturindantoki.
Ibindi: Nyuma yakazi, koga kandi uhindure imyenda.Bika imyenda yanduye uburozi ukwayo hanyuma uyikoreshe nyuma yo gukaraba.Komeza ingeso nziza z'isuku.
Ingamba zambere zubutabazi
Guhuza uruhu: Ako kanya kwoza amazi byibuze muminota 15.Niba hari umuriro, shaka kwivuza.
Guhuza amaso: Ako kanya uzamure ijisho hanyuma woge n'amazi atemba cyangwa saline physiologique byibuze muminota 15.
Guhumeka: Kura vuba aha hantu ujyane umwuka mwiza.Komeza inzira z'ubuhumekero zitabujijwe.Kora ubuhumekero bwa artile nibiba ngombwa.Shakisha ubuvuzi.
Ingestion: Iyo umurwayi akangutse, kwoza umunwa ako kanya, ntutere kuruka, kandi unywe amata cyangwa umweru w'igi.Shakisha ubuvuzi.
Uburyo bwo kuzimya umuriro: ifuro, dioxyde de carbone, umucanga, ifu yumye.
5.Ububiko
Ubike mu bubiko bukonje, bwumye, kandi buhumeka neza.Irinde ibishashi n'amasoko y'ubushyuhe.Ibipfunyika bigomba gufungwa kandi bikarindwa ubushuhe.Igomba kubikwa ukwayo na acide, amine, alcool, esters, nibindi, kandi ikirinda kuvanga ububiko.Ahantu ho guhunika hagomba kuba hafite ibikoresho bikwiye kugirango bitangire.
Ubuhanga bwo kubara 6 Guhindura amakuru
1. Agaciro kerekana kubara hydrophobique kubara (XlogP): Ntayo
2. Umubare w'abaterankunga ba hydrogen: 0
3. Umubare wa resitora ya hydrogen yakira: 0
4. Umubare wububiko bwimiti izunguruka: 0
5. Umubare wa tautomers: Ntayo
6. Ubuso bwa molekile ya topologiya yubuso: 0
7. Umubare wa atome ziremereye: 5
8. Amafaranga yo hejuru: 0
9. Ingorabahizi: 19.1
10. Umubare wa Atoto ya Isotope: 0
11. Menya umubare wibigo byubaka atome: 0
12. Umubare wibigo byubaka atome bitazwi: 0
13. Menya umubare wibikoresho bya stereo yububiko: 0
14. Umubare wa stereocenters ya chimique itazwi: 0
15. Umubare wimigabane ya covalent: 1
Igihe cyo kohereza: Gicurasi-25-2023